1. Beam is the horizontal Member which transfer loads from slabs to column, beam is part of RCC frame structure or Structural steel structure.
2. Frame is composite structure made of Horizontal & vertical supports to bear or transfer the load. like RCC or Structural steel Frame.
refer below link to understand the components as shown in PPT,
Source of Image is = UndeerstandConstruction.com
Concrete Frame Construction | Concrete Frame Structures